Charles Friedel

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چکیده

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Analysing Friedel averages and differences.

Various practical applications of the average (A) and difference (D) of Friedel opposites are described. Techniques based on the resonant-scattering contribution to Friedel differences are applied to see whether a crystal is centrosymmetric or not, and to determine the point group of the crystal. For the validation of a structural study, plots of A(obs) against A(model), and D(obs) against D(mo...

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A previous analysis of the average intensity and mean-square intensity difference of Friedel opposites, confined to the space group P1 [Flack & Shmueli (2007). Acta Cryst. A63, 257-265], is here extended to all the non-centrosymmetric space groups. The present analysis presumes purely non-centrosymmetric content of the unit cell. An important result of this study is that the average intensity a...

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ژورنال

عنوان ژورنال: Educación Química

سال: 2009

ISSN: 0187-893X

DOI: 10.1016/s0187-893x(18)30049-1